There is no straight (should I say “easy”) way to export Outlook mails to Thunderbird. Using Thunderbird’s import from Outlook did not work since quite a few emails came up as raw HTML, and I had to manually change Automatic encoding detection to OFF, Universal to see the contents each time.
A sure-shot (well… which took me 99% of the) way was Outlook –> Import into Outlook Express –> Import into Thunderbird. This worked, but with one sad issue – non-English attachment names are not as original. If you can live with that, then this is the surest way to go !
Few references which helped-
Import .pst files – MozillaZine KB